Research topics

The Fujita Laboratory > Research topics > Phenomena within self-assembeld molecular space

Phenomena within self-assembeld molecular space

Molecular recognition


 

References

  • "AND/OR Bimolecular Recognition"
    M. Yoshizawa, M. Tamura, M. Fujita
    J. Am. Chem. Soc. 2004, 126, 6846-6847.

  • "Sequence-Selective Recognition of Peptides within the Single Binding Pocket of a Self-Assembled Coordination Cage"
    S. Tashiro, M. Tominaga, M. Kawano, B. Therrien, T. Ozeki, and M. Fujita
    J. Am. Chem. Soc. 2005, 127, 4546-4547.

Accumulation of planar molecules


 

References

  • "Discrete Stacking of Large Aromatic Molecules within Organic-Pillared Coordination Cages"
    M. Yoshizawa, J. Nakagawa, K. Kumazawa, M. Nagao, M. Kawano, T. Ozeki, and M. Fujita
    Angew. Chem. Int. Ed. 2005, 44, 1810-1813.

  • "Metal-Metal d-d Interaction through the Discrete Stacking of Mononuclear M(II) Complexs (M = Pt, Pd, and Cu) within an Organic-Pillared Coordination Cage"
    M. Yoshizawa, K. Ono, K. Kumazawa, T. Kato, and M. Fujita
    J. Am. Chem. Soc. 2005, 127, 10800-10801.

  • "Room-Temperature and Solution-State Observation of the Mixed-Valence Cation Radical Dimer of Tetrathiafulvalene, [(TTF)2]+・, within a Self-Assembled Cage"
    M. Yoshizawa, K. Kumazawa, and M. Fujita
    J. Am. Chem. Soc. 2005, 127, 13456-13457.

Spin-spin interaction


 

References

  • "Cavity-Induced Spin-Spin Interaction between Organic Radicals within a Self-Assembled Coordination Cage"
    K. Nakabayashi, M. Kawano, M. Yoshizawa, S. Ohkoshi, and M. Fujita
    J. Am. Chem. Soc. 2004, 126, 16694-16695.

  • "A pH-Switchable Through-Space Interaction of Organic Radicals within a Self-Assembled Coordination Cage"
    K. Nakabayashi, M. Kawano, and M. Fujita
    Angew. Chem. Int. Ed. 2005, 44, 5322-5325.

  • "Metal-Metal d-d Interaction through the Discrete Stacking of Mononuclear M(II) Complexs (M = Pt, Pd, and Cu) within an Organic-Pillared Coordination Cage"
    M. Yoshizawa, K. Ono, K. Kumazawa, T. Kato, and M. Fujita
    J. Am. Chem. Soc. 2005, 127, 10800-10801
 

Stabilization of labile molecule


 

References

  • "Multicomponent Assembly of a Pyrazine-Pillared Coordination Cage That Selectively Binds Planar Guests by Intercalation"
    K. Kumazawa, K. Biradha, T. Kusukawa, T. Okano, M. Fujita
    Angew. Chem. Int. Ed. 2003, 42, 3909-3913.

  • "Endohedral Clusterization of Ten Water Molecules into a Molecular Ice within the Hydrophobic Pocket of a Self-Assembled Cage"
    M. Yoshizawa, T. Kusukawa, M. Kawano, T. Ohhara, I. Tanaka, K. Kurihara, N. Niimura, and M. Fujita
    J. Am. Chem. Soc. 2005, 127, 2798-2799.

  • "Room-Temperature and Solution-State Observation of the Mixed-Valence Cation Radical Dimer of Tetrathiafulvalene, [(TTF)2]+・, within a Self-Assembled Cage"
    M. Yoshizawa, K. Kumazawa, and M. Fujita
    J. Am. Chem. Soc. 2005, 127, 13456-13457.
 

Photochemical reaction


 

References

  • "Cavity-Directed, Highly Stereoselective [2+2] Photodimerization of Olefins within Self-Assembled Coordination Cages"
    M. Yoshizawa, Y. Takeyama, T. Kusukawa, M. Fujita
    Angew. Chem. Int. Ed. 2002, 41, 1347-1349.

  • "Cavity-Directed Synthesis within a Self-Assembled Coordination Cage: Highly Selective [2+2] Cross Photodimerization of Olefins"
    M. Yoshizawa, Y. Takeyama, T. Okano, and M. Fujita
    J. Am. Chem. Soc. 2003, 125, 3243-3247.

  • "Alkane Oxidation via Photochemical Excitation of a Self-Assembled Molecular Cage"
    M. Yoshizawa, S. Miyagi, M. Kawano, K. Ishiguro, and M. Fujita
    J. Am. Chem. Soc. 2004, 126, 9172-9173.

Condensation reaction


 

References

  • "Cavity-Directed Synthesis of Labile Silanol Oligomers within Self-Assembled Coordination Cages"
    M. Yoshizawa, T. Kusukawa, M. Fujita, S. Sakamoto, K. Yamaguchi
    J. Am. Chem. Soc. 2001, 123, 10454-10459.